Topotactic phase transformation of 4H-CuyTa1.10S2into 4H-Ta1.10S2
نویسندگان
چکیده
منابع مشابه
Stabilization of 4H hexagonal phase in gold nanoribbons
Gold, silver, platinum and palladium typically crystallize with the face-centred cubic structure. Here we report the high-yield solution synthesis of gold nanoribbons in the 4H hexagonal polytype, a previously unreported metastable phase of gold. These gold nanoribbons undergo a phase transition from the original 4H hexagonal to face-centred cubic structure on ligand exchange under ambient cond...
متن کامل3-[(4-Oxo-4H-thiochromen-3-yl)methyl]-4H-thiochromen-4-one
The title mol-ecule, C19H12S2O2, lies on a twofold rotation axis. The thio-chromonone unit is essentially planar, with a maximum deviation of 0.0491 (14) Å. The dihedral angle between the thio-chromenone ring systems is 64.48 (4)°. In the crystal, there are weak π-π stacking inter-actions, with a centroid-centroid distance of 3.7147 (9) Å.
متن کاملAnnealing of multivacancy defects in 4H-SiC
The annealing behavior of defects observed in electron paramagnetic resonance EPR and photoluminescence PL is discussed. We consider the divacancy the P6/P7 EPR centers and a previously unreported EPR center that we suggest is a VC-VSi-VC trivacancy and their relationship with each other and with the UD1–3 series of PL lines near 1 eV. We observe that the divacancy and the UD2 PL lines annealin...
متن کاملStructure of a new bulk Ti5Al2C3 MAX phase produced by the topotactic transformation of Ti2AlC
Upon annealing cold-pressed Ti2AlC, -325 mesh powders, at 1500 °C for 8 h in argon, the resulting partially sintered sample contained 43(±2) wt.% of the layered ternary carbide Ti5Al2C3. Herein, the X-ray powder diffraction pattern of Ti5Al2C3 is reported for the first time. Its structure and stoichiometry are confirmed through high-resolution transmission electron microscopy. This phase has a ...
متن کاملSynthesis and Antimicrobial Evaluation of 4H-Pyrans and Schiff Bases Fused 4H-Pyran Derivatives as Inhibitors of Mycobacterium Bovis (BCG)
The focus of our study is the synthesis and biological activity evaluation of a series of 4H-Pyran compounds and schiff bases fused 4H-Pyran derivatives which are known to possess a wide variety of biological activities. In this paper at first a simple and efficient one-pot synthesis of 4H-Pyran s from the three-component reaction between malononitrile, aldehydes, and active methylene compounds...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2010
ISSN: 0108-7673
DOI: 10.1107/s010876731009375x